The PNY FX1500 video version has composite and S-video outputs, if you want component output you might be interested in the PNY FX560 video version, it has a BOB with composite, S-video and component out. with the FX cards you can have either two computer monitors or 1 computer and one video
There is nothing wrong with a 965 chipset mobo,
If you are going to use AFX use as much memory as the board will hold, just make sure you set the 3gig switch, also use the fastest processor you can afford