Hey Don,
It’s a little bit unclear to me weather you need help with the key or the spill… I’ll give you advice for both and maybe I can help you out!
In the world of keying/spill suppression you always want to separate out these steps, particularly in Keylight which has a VERY sensitive and aggressive spill suppression algorithm. You also want to often pull your matte in multiple keys (though this isn’t always necessary). It’s a bit hard to explain this in text without showing you but I’ll do the best I can!
Basically you apply keylight to your footage and get a good looking key (looking at Screen Matte in the View dropdown). Then if you need to do any roto on top with either a black layer or white layer, or even a second key if needed (which it sounds like you will). Then without switching your View dropdown pre-compose the whole lot – keys and rotos.
Now pull your original un-keyed footage back into your comp and start your despill. I recommend two approaches – first apply Keylight, select your Screen Color and change your Screen Matte -> Clip White to 1 (thus only despilling and not keying at all). Second if that doesn’t look good (it rarely does) try this free plug-in: https://cinegobs.com/uncategorized/release-spill-suppression-for-after-effects-64-bit-cs5. The last is a magical plug-in that will work 90% of the time!
Now put your pre-comp (which is now your matte) on top of your newly despilled foreground and set your despilled clip to “Luma Matte” your pre-comp.
Boom! A little light-wrap, some further color correction, and you should be good to go!
– Spencer
PS with really spill’d footage you might also need to do a degrain. I would do this on your clip, pre-comp it, and do all of the above with your pre-comp instead of the raw source. I also sometimes just pre-render out the degrained plate to speed things up.