That digital effect that you are looking for is called chromatic distortion. It has nothing to do with DOF, it has to do with the image sensor of the camera (called a CCD). The Photoshop manual talks a little about it in relation to camera RAW and how to remove it. You can, however, use those settings to add it, not remove it (just by ‘overcompensating’). The only problem is that you would have to open the image in Camera RAW, which means that you would have to batch edit an amination (which is possible).
I am sure there is an easier way to handle this, but that is what I would suggest.
– Spencer
PS
I just remembered that I saw a tutorial a little bit ago that shows you how to take a depth pass into photoshop and you can use it to do a rack defocus (animation and all). I am currently trying to find how to do this in AE for more animation ability and control