Your question is somewhat confusing, because first you say:
>I would like to make the Blur Amount slider on the Master Control layer the control for the Blur Radius which is located on the Square layer
But then you say:
>…and the necessary expression would be written to the Blur Amount slider on the Master Control layer.
So I’m not sure what you’re after. To be clear though, an expression can only affect the property hosting the expression, so if you want the expression to control the Blur Radius on the Square layer, that’s where the expression would have to be applied.