DV25 is DV25 is DV25 no matter where it originates from. A straight Firewire transfer is just that a transfer of data. If it comes over an SDI connection is it still the same quality. It’s not adding pixels, or anti-aliasing them, simply transfering them. While some decks “upsample” to 4:2:2, there is really no additional data added. Take a picture of a pile of bricks stacked three high a pyramid shape and you will easily see the “aliasing” at the edges of the bricks. Take a picture at a higher resolution and thise edges are still there. The higher sampling rate is not going to fill in the dges and make the stack look smoother. Same principal applies to video.
While ther may be some differences in codecs, the main reason why an uncompressed time looks better is the fact that everything else overlaying it looks better. If you add a graphic to a DV timeline, it will look a little soft at the edges. If you add the same graphic over an uncompressed timeline, it will look better, all things being equal. The underlying footage will look the same, more or less.
While I won’t argue that there might be slight differences in the codecs involved, there really isn’t that much of a difference between transferring via Firewire or SDI. You will see a major difference, though, between SDI and component analog captures. The former is again just a transfer of data, while the later involdes converting the three analog signals into a digital format for processing.
There are filters that can “smooth” a 4:1:1 clip giving the appearance of 4:2:2 sampling and hence the appearance of sharper video. Nattress has a pretty nifty filter that’s always evolving and getting better. I know just enough to be dangerous on the subject. If you really want to get into a technical argument (discussion?), drop him an email on the subject. He explains it beautifully.
Just my 2