Vegas does “detect” both cards, but as far as my experience goes it can only utilize one card at a time.
I am running a 6990 which is identified as two separate cards.
I can only select one of them in the GPU acceleration option.
When rendering a video, only one of the cores have a significant jump in temperature(all though the unused core also increase in temp due to sharing the same cooling block as the active one).
There might be ways around this, but it does not work in SLI “out of the box”.