Thanks for all your responses guys.
I have had some experience with greenscreen in the past and agree with you guys that lighting is crucial! Luckily i am shooting in a proper studio environment with excellent lighting capabilities.
I have made the final decision to go with the DVCPro50 format. In reply to your comment Joseph, DVCPro50 is actually 4:2:2, running at 50 Mbits/sec and would match, if not outperform the older BetaSP format, judging from examples of footage that I have seen.
I would maybe have considered sticking with regular DV but time is a big factor for me too. If I have to spend 4 times longer to pull a clean key (on over 80 seperate shots for good measure!) than that is a big problem. I have fun times ahead, keying footage,finishing textures+lights for environments, matching camera moves in 3D, compositing, colour grading, visual effects, editing, sound design…anyways, enough whining from me!
Thanks guys!