The dual-core G5’s, (not just dual processors) were the first models to have PCIe (express). The dual-processor machines preceded those with dual-core processors.
There were no quad 2.7 GHz. After the dual-processor 2.7 came out–and it was PCI-X–came the 2.5 GHz dual-core machines, up to the Quad (two processors or dual-core each) at 2.5 GHz. These dual-core machines were the first G5’s to have PCI Express (PCIe). The speed of the processors actually when down when the dual-core chips were released.