VOB from dvd recorders are known to cause issues.
If you have a camera with analog in connect the dvd player to the camera and the camera with firewire to the pc. This way you can capture dv-avi.
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Adobe Certified Expert Premiere Pro
As mpeg is a compressed file format the changes of getting out of sync with large file is not uncommen.
Chopping it up into subclips might do the trick.
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Adobe Certified Expert Premiere Pro