SO after trying every bit of advice I could find on the web I still could not open CS6 Media Encoder or Premiere. So, I booted into the recovery partition of my iMac. I used disk utilities and ran “Repair Permissions” three times. Rebooted and both programs now load.
I tried:
Reinstall of CS6
Deleting Quicktime Plug-ins
New User Account (Programs did load with this, however, I didn’t want to transfer all my media over to this account)
Reset Admin Password through Terminal in recovery mode.