You can make any video file constrain itself to fit the entire comp window by making sure the video is selected in the timeline and hitting ctrl+alt+f. However, it will not keep the current aspect ratio (dimensions in relation to eachother) the same so your footage will most likely look skewed.
If you want to make a video file larger but don’t want to lose it’s aspect ratio, scale up past 100% under the transform>scale twirldown menu. Just remember that whenever you scale up past 100% after effects is interpolating the extra information… i.e. a loss in quality from the original footage.
peace,
Michael