You can time a GV100 with color bars and come very close to what you would do with a WF/Vector Scope.
If your do not have the regen option card you will need a sync generator that produces the external drive inputs to the GV100. With the option installed you only need color black to the ref input. Use the appropriate generator that also includes color bars.
Ideally you will run each input through something that will allow you to adjust gain, or the source will have such an adjustment.
You will need to run color black to all of your sources. It is best to take this sync signal into a DA and then fan out to each source from there. Other option is if each item has a loop through and you can chain the sync from one to the next.
Run color bars into one of the inputs and your sources to the others. Create a spit screen with the color bars on the bottom and one other source on top. Set your source (camera, etc.) to generate its internal color bars, or (deck) play content with color bars). Split the screen on the large white block at the bottom. Adjust your gain until the two halves of the white block match.
Reposition the split in the center of the upper bars.
Adjust the horizontal phase of the source until the bars align vertically. If one source has fatter bars and only one place will align pick one to the left, like between grey and yellow.
Adjust the coarse phase of your source until you get bars at the top that are as close as you can get to your standard on the bottom. Then adjust the fine phase until they match.
Adjust the color or EQ adjustment of your source until the bars blend as best possible with no visible split.
Repeat steps as needed to refine the adjustments.
You may never get it perfect. NTSC = Never Twice Same Color, but once you get it as close as you can you are good to go.
If your picture jogs at the end of a transition you need to fine tune the Horizontal phase.
Also, there are course and fine phase adjustments in the GV100. Use them only to calibrate the standard from your generator so that the standard appears correct. Without a waveform monitor you will have to decide with your eye if the colors are correct. With experience you will get close and without bars recorded to your master and a monitor to evaluate them, there will be few who could challenge your colors.