Green is usually the better color for video cameras, the luminance signal mostly comes from the green channel and the blue channel is typically noisier than the green.
Yes you’re going to have blocky edges, that’s part and parcel of working with 4:1:1 video. Try ultimatte or keylight or Serious Magic Ultra or some other high-end keying tool, they can go a long ways towards delivering cleaner keys from a DV source.
—————–
Get the most from your DVX camera. The DVX Book and DVX DVD are now available on ebay and at Amazon (https://www.fiftv.com/db)