Ever seen the “clap-board” they use on a film set, for the start of a take? While the black-board part is used to index takes, the “clap” itself is for audio synchronization — it’s easy to match a sharp audio event.
And easier, still, when you’re in an NLE and can actually eye-ball the audio. Audio sampling is, of course, far finer grained than video, too, so it’s the place to look. You can usually find a good audio sync point, but if you can’t, next time, create one — a loud clap or something before you start. But for any kind of performance, there’s generally some quiet-leading-to-loud portion, mic feedback, a cough in the audience, a cymbal clash, something to use for syncing up cameras.
For any major event, like a wedding shoot, I’m likely to be starting and stopping cameras all the time. I keep one digital audio recorder (Tascam DR-1) going throughout the entire event, though — much easier to sync multiple video clips to a foundation, than to each other.
For pros doing this on a regular basis (and using Vegas Pro), there’s the Plural Eyes plug-in from Singular Software, which does pretty decent audio synchronization automatically. Not cheap ($150), but you could save hours per project if you have complicated shoots.
-Dave